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Керамика из нитрида кремния(Si3N4)

Керамика из нитрида кремния(Si3N4)

Silicon Nitride Ceramics: Types, Properties, and Applications of Advanced Nitride Materials
Silicon Nitride Ceramics are advanced ceramics primarily composed of nitrides, with two main crystalline forms: α-silicon nitride and β-silicon nitride. Depending on the sintering process, they are categorized into hot-pressed silicon nitride and reaction-bonded silicon nitride.

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Sintering Processes

Hot-Pressed Silicon Nitride

    • This type is made by pressing silicon nitride powder into a mold and sintering it at 1700°C under 20-30 MPa pressure.
    • It produces dense, pore-free ceramics with excellent flexural strength and toughness.

Reaction-Bonded Silicon Nitride

    • It starts with silicon (Si) or silicon nitride (Si₃N₄) powder, which is shaped and then heated in a nitrogen-rich atmosphere to form silicon nitride (Si + N₂ → Si₃N₄).
    • The final products are highly precise in dimensions but contain 20%-30% porosity, which makes them less strong, hard, and tough compared to hot-pressed silicon nitride.

Among all ceramics, silicon nitride offers the best thermal shock resistance.


Main Features из Silicon Nitride Ceramic

  • Excellent self-lubrication and wear resistance
  • Low thermal expansion coefficient
  • Outstanding thermal shock resistance
  • High hardness and a low friction coefficient (0.1-0.2)
  • Good chemical stability and electrical insulation

Silicon Nitride Ceramic Property Chart

Недвижимость Units Silicon Nitride (Si₃N₄)
Общие сведения
Цвет Black
Газопроницаемость атмс-куб/сек Gas tight < 10⁻¹⁰
Поглощение воды % 0
Плотность г/см³ 3.20
Механические свойства
Hardness Vickers 500 gm GPa (kg/mm²) 15 (1529)
Hardness (R45N) 83
Fracture Toughness( Notched Beam) MPa·m¹/² 6
Прочность на изгиб (MOR) MPa (psi x 10³) 900 (130)
Tensile Strength @ RT MPa (psi x 10³) 537 (78)
Compressive Strength @ RT MPa (psi x 10³) 2500 (362)
Elastic Modulus GPa (psi x 10⁶) 300 (44)
Poisson’s Ratio 0.28
Тепловые свойства
C.T.E. (25 – 600°C) x 10⁻⁶/°C 2.9
Thermal Conductivity @ RT W/m·K 29
Max Use Temp Фаренгейт (°F) 2462
Max Use Temp Цельсий (°C) 1350
Электрические свойства
Диэлектрическая прочность В/мил 300
Диэлектрическая проницаемость на частоте 1 МГц 9.1
Volume Resistivity, 25°C Ом-см > 10¹⁴

* Значения представляют собой типичные свойства материала и могут изменяться в зависимости от конфигурации изделия и процесса производства,
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Silicon Nitride Ceramic Applications

Hot-Pressed Silicon Nitride (HPSN)

  • Cutting tools
  • Simple-shaped parts for wear and high-temperature applications
  • Bearing components

Reaction-Bonded Silicon Nitride (RBSN)

  • Ideal for complex shapes requiring high precision
  • Sealing rings in the petrochemical industry
  • Gas turbine rotor blades

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